Heat treating to correct tiller is done once the bow is braced, not before.
Before bracing, you want to try and preempt issues like reflex and deflex. Reflexed areas are left slightly thinner, deflexed areas slightly thicker.
So basically, leave maybe 2mm extra thickness on the belly in that deflexed area, take everything else down to exact finished dimensions and check, check and check again the eyeline, looking for swells, dips etc that shouldn't be there. Get all of those sorted, until you're absolutely sure the bow is ready (I tend to ask myself if I'd sell it and if the answer is yes, it's ready!) and then get the horns on, brace it up and see what's happening.
That's the stage where you bring in the heat gun, charcoal etc to temper the areas that are bending too much at brace height.